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CAS 221615-75-4

1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)ethan-1-one

Codes: ETOR-014

Application context (from source-drug indications)

OsteoarthritisEtoricoxib痛风性关节炎EtoricoxibDysmenorrhoeaEtoricoxibRheumatoid arthritisEtoricoxibAnkylosing spondylitisEtoricoxibParkinson's diseaseEtoricoxib

Source drugs (routes using this intermediate)

DrugTierExpiry
EtoricoxibTier C — Watch / trade-

Position in synthesis routes (up/downstream chain)

Ordered by route registration; left → right is the synthesis direction. The highlighted node is the current CAS; others link to their own profiles.

EtoricoxibOptimised routesteps: 8total yield: 8.42 g
methyl 6-methylnicotinate→N-methoxy-N,6-dimethylnicotinamide→6-methylnicotinaldehyde→diphenyl ((6-methylpyridin-3-yl)(phenylamino)methyl)phosphonate→4-(methylsulfonyl)benzaldehyde→(E)-N-(1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)vinyl)aniline→1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)ethan-1-one→ETOR-015→(Z)-4-chloro-3,5-bis(dimethylamino)-1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)pent-4-en-1-one→(2Z,4Z)-4-chloro-5-(dimethylamino)-1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)penta-2,4-dien-1-one
EtoricoxibOptimised routesteps: 3total yield: /
EtoricoxibOptimised routesteps: 4total yield: /
1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)ethan-1-one→methyl (E)-2-chloro-3-(tosyloxy)acrylate→3-chloro-6-(6-methylpyridin-3-yl)-5-(4-(methylsulfonyl)phenyl)-2H-pyran-2-one→5-chloro-6'-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3'-bipyridin]-6-ol→5-chloro-6'-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3'-bipyridin]-6-yl 4-methylbenzenesulfonate
EtoricoxibOptimised routesteps: 1total yield: 1.81 g
1-(6-methylpyridin-3-yl)-2-(4-(methylsulfonyl)phenyl)ethan-1-one→(Z)-2-chloro-3-hydroxyacrylaldehyde

Intermediates available on this site

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